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methyl cyanoacrylate polymer

Polymer whiskers grown from methyl 2-cyanoacrylate vapor. Polymer Physics. Using glacial acetic acid (3.7%-7.1% by volume), the polymerization time was prolonged from 2.3 sec to 7.8 sec. METHYL 2-CYANOACRYLATE is an unsaturated aliphatic nitrile and acrylate ester. Draw the structure of the polymer formed by methyl cyanoacrylate. Permabond 101 followed not too long after that. Polymer poly methyl cyanoacrylate is used in medical and veterinary applications. Làm nóng polymer gây ra hiện tượng phân hủy MCA đã được xử lý, tạo ra các sản phẩm khí gây kích ứng mạnh cho phổi và mắt. Smith-Johannsen RI. B refers to a base. Yanyan Cui † ‡, Jingchao Chai ‡ §, Huiping Du ‡ §, Yulong Duan ‡ §, Guangwen Xie * †, Zhihong Liu * ‡ §, and ; Guanglei Cui * ‡ § When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. When made on an industrial scale [3], the monomer polymerises after the condensation reaction because the monomer is extremely reactive in the presence of base. Stylized skeletal formula: Atoms - 2C9JW5T from Alamy's library of millions of high resolution stock photos, illustrations and vectors. Polymeric cyanoacrylates start to decompose thermally (unzipping) at temperatures approaching 140°C. The preparation of high polymers of methyl a-cyanoacrylate by free-radical initiation does not seem to have been adequately described in the literature. Advanced Rheology Institute, Department of Polymer Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China *E-mail: [email protected] n Poly(2-propenoic acid, 2-cyano-, methyl ester). II. Độ an toàn. Methyl cyanoacrylate is the main ingredient in super glue. Learn more about Hansen Solubility Parameters (HSP) and their use in … The number and character of the … Physical Data. Chemistry Chemistry Two molecules used in the polymer industry are azodicarbonamide and methyl cyanoacrylate. Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries. if 100% efficiency of initiation by azobisisobutyronitrile is assumed. Poly(methyl methacrylate)-block-poly(n-butyl acrylate)-block-poly(methyl methacrylate) triblock copolymers (MnBM) have been synthesized by the sequential controlled radical polymerization (atom transfer radical polymerization, ATRP) of n-butyl acrylate (n-BuA) followed by methyl methacrylate (MMA). The initiation of polymerization depends on an alkaline medium and can be inhibited with the addition of small amounts acid. The ratio of kp2/kt is approximately 0.021 at 60°C. Find products that are predicted to be compatible with Methyl 2-cyanoacrylate. See NIOSH Pocket Guide to Chemical Hazards (DHHS/NIOSH 97-140, 1997) p 204. Procedures for the preparation of the monomer,'S2 stabilization against anionic polymer- ization,2 and some properties of the bulk polymer' have appeared in the patent literature. Poly(methyl cyanoacrylate) Poly(ethyl cyanoacrylate) Poly(butyl cyanoacrylate) Polymer Properties Database Free Polymer Information Source. This list of compatible products is generated out of estimated HSP values. Copolymerization studies, Journal of Applied Polymer Science" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Knovenagel Reaction showing the synthesis of methyl-2-cyanoacrylate. Permabond 910 was the original methyl cyanoacrylate. Cite this entry as: Gooch J.W. Under the conditions of the thermogravimetric analysis technique employed, weight loss kinetics appear to be governed by diffusion of monomer vapour through the liquid sample. 191289-03-9 - 2-Propenoic acid, 2-methyl-, polymers with acrylonitrile, bisphenol A, butadiene, 3-carboxy-1-cyano-1-methylpropyl-terminated acrylic acid-acrylonitrile-butadiene polymer, 3-carboxy-1-cyano-1-methylpropyl-terminated polybutadiene, epichlorohydrin and 1,5-naphthalenediol - Searchable synonyms, formulas, resource links, and other chemical information. Methyl cyanoacrylate ít gặp hơn ethyl cyanoacrylate. Years ago, I was told to use methyl cyanoacrylates for metal and ethyl for everything else. The majority of super glues are either methyl or ethyl cyanoacrylate based. Research in this laboratory further showed that the P-14C-tagged methyl a-cyanoacrylate polymer was degraded gradually in vivo4 and was excreted in the urine and feces with none of the radioactive entities being retained in vital tissues or organs. While growing, the fibers seem to be chemically more active at their ends than along their sides, with this chemical specificity leading to a linearly ordered polymer structure. 2-Octyl cyanoacrylate (OCA) was mixed with a solution containing poly(3-methacryloyloxypropyltris(trimethylsiloxy)silane-co-methyl methacrylate-co-isooctyl acrylate) (PSS1), polyphenylmethylsiloxane and hexamethyldisiloxane. Polymers of the former compound, commonly referred to by the abbreviation HEMA, soften upon absorption of water; they are used to make soft contact lenses. Two molecules used in the polymer industry are azodicarbonamide and methyl cyanoacrylate. It has the following composition: 54.05% carbon, 12.61% nitrogen. It is the main component of cyanoacrylate glues and can be encountered under many trade names. MCA polyme hóa nhanh chóng trong sự tham gia của độ ẩm. Filaments of methyl 2-cyanoacrylate polymer were developed from the vapors of the monomer. 4.54% hydrogen, and 28.80% oxygen. It is soluble in acetone, methyl ethyl ketone, nitromethane, and methylene chloride. Methyl cyanoacrylate (MCA; CAS No. Nó hòa tan trong axeton, methyl ethyl ketone, nitromethane, và dichloromethane. HEMA and cyanoacrylate polymers. In: Gooch J.W. 137-05-3) and ethyl cyanoacrylate (ECA; CAS No. As the glue sets, methyl cyanoacrylate polymerizes across the carbon – carbon double bond. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. While growing, the fibers seem to be chemically more active at their ends than along their sides, with this chemical specificity leading to a linearly ordered polymer structure. When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. 2 cyanoacrylate (IBeA) polymerizes by an anionic mechanism. Polymers Index. Physical property data on over two hundred and fifty polymers. n. Poly(2-propenoic acid, 2-cyano-, methyl ester) ( See image). 25067-29-2 - Poly(methyl cyanoacrylate) - Similar structures search, synonyms, formulas, resource links, and other chemical information. Calculate the empirical formula for polymethyl cyanoacrylate (Enter the elements in the order C,H, N, O.) (eds) Encyclopedic Dictionary of Polymers. Their structures are Azodicarbonamide is used in forming polystyrene. The resultant liquid adhesives were cast onto Teflon™ sheet and … Download this stock image: Poly(methyl cyanoacrylate) polymer, chemical structure. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. (2011) Poly(methyl cyanoacrylate). Nitriles may polymerize in the presence of metals and some metal compounds. Plastic Resins. Read "Methyl α‐cyanoacrylate. A practical determination of these HSP values would provide higher certainty. Filaments of methyl 2-cyanoacrylate polymer were developed from the vapors of the monomer. It takes the shape of a polymer (plastic) resin in its cured form and a monomer in its uncured form. Application: Methyl cyanoacrylate is generally used to bond mostly metals for wire tacking and fixturing parts before riveting or welding. METHYL CYANOACRYLATE AND ETHYL CYANOACRYLATE Please note that the lay out and pagination of this pdf file are not necessarily identical to those of the printed CICAD First draft prepared by Mr Richard Cary, Health and Safety Executive, Liverpool, United Kingdom Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization, … Commercially important cyanoacrylate monomers include methyl 2-cyanoacrylate, ethyl-2-cyanoacrylate, n-butyl cyanoacrylate and 2-octyl-2-cyanoacrylate. Polymerized (set) form of methyl cyanoacrylate instant glue. respectively. Additional Names: Poly(methyl 2-cyanoacrylate) CAUTION: Potential symptoms of overexposure are irritation of eyes, skin, nose; blurred vision, lacrimation; rhinitis. The polymer provides a strong bond between the two surfaces. Methyl α‐cyanoacrylate, when suitably inhibited by Lewis acids against anionic polymerization, can be polymerized readily with free‐radical initiators to form hard, clear, high molecular weight polymers. That simple saying served well me for many years. This means that the polymer needs to be cracked and forms a crude mixture of the monomer and bits of the broken-up polymer. Resins Index . This solution shall be abbreviated as SOL1 (solution one) in the following references. Commercial commodity and engineering plastic resins. Chemistry Chemistry “Super glue” contains methyl cyanoacrylate, which readily polymerizes upon exposure to traces of water or alcohols on the surfaces to be bonded together. When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. Methyl cyanoacrylate Azodicarbonamide is used in forming polystyrene. Industry– PCB for wire … Related in structure to methyl methacrylate are the monomers 2-hydroxyethyl methacrylate and methyl cyanoacrylate, denoted by the chemical formulas. Cyanoacrylate adhesives offer much enhanced toughness by the inclusion of elastomeric materials capable of undergoing phase separation on curing. The latter compound, usually referred … Their structures are Azodicarbonamide Methyl cyanoracy late Azodicarbonamide is used in forming polystyrene. 7085-85-0) are clear, colourless liquids that react readily with water to form solid polymers. Thermal degradation of methyl and ethyl cyanoacrylate polymers of number‐average molecular weights 370–1350 is shown to proceed by depolymerisation at temperatures in the range 140°–180°C. You’ve likely come across the trademarked adhesive known as Super Glue, which you may not have realized is also, cyanoacrylate, it’s generic name. Physical and mechanical properties of polymers. In its simplest form, cyanoacrylate can be thought of as super glue — a quick-drying, strong-bonding clear adhesive. It was formulated over 60 years ago and is still sourced to meet aerospace, automotive, and many other company specific specifications. Ethyl cyanoacrylate (ECA), a cyanoacrylate ester, is an ethyl ester of 2-cyano-2-propenoic acid.It is a colorless liquid with low viscosity and a faint sweet smell in pure form. The RD(50) values of methyl-2-cyanoacrylate, ethyl-2-cyanoacrylate, isopropyl-2-cyanoacrylate and 2-methoxyethyl-2-cyanoacrylate were 1.4, 0.7, 0.6 and 1.0 p.p.m. Thermally resistant ethyl cyanoacrylate adhesives. Monomers include methyl 2-cyanoacrylate, ethyl-2-cyanoacrylate, n-butyl cyanoacrylate and 2-octyl-2-cyanoacrylate ratio of kp2/kt is approximately 0.021 at.... 7.8 sec more about Hansen Solubility Parameters ( HSP ) and their use in … HEMA cyanoacrylate... 2.3 sec to 7.8 sec is soluble in acetone, methyl cyanoacrylate by volume ), the polymerization time prolonged... By an anionic mechanism agents such as peroxides and epoxides and fifty polymers polymerization... % -7.1 % by volume ), the polymerization time was prolonged from 2.3 to! Clear adhesive see NIOSH Pocket Guide to chemical Hazards ( DHHS/NIOSH 97-140, 1997 p... % nitrogen its uncured form veterinary applications nitriles are generally incompatible with acids ; mixing nitriles with strong acids... Gia của độ ẩm ) form of methyl a-cyanoacrylate by free-radical initiation not... Clear, colourless liquids that react readily with water to form solid polymers của... Trong axeton, methyl ester ) % -7.1 % by volume ), the polymerization was. Medium and can be encountered under many trade names over two hundred and fifty polymers carbon – carbon double.. Other oxidizing agents such as peroxides and epoxides meet aerospace, automotive, and other chemical.... Polymers of methyl a-cyanoacrylate by free-radical initiation does not seem to have been adequately described in the provides! Acids ; mixing nitriles with strong oxidizing methyl cyanoacrylate polymer can lead to extremely violent reactions or welding 137-05-3 and! Efficiency of initiation by azobisisobutyronitrile is assumed toward Flexible Lithium Batteries glue sets, methyl )!, usually referred … polymer Poly methyl cyanoacrylate is used in methyl cyanoacrylate polymer order C,,. If 100 % efficiency of initiation by azobisisobutyronitrile is assumed polyme hóa nhanh chóng trong sự gia! Bond mostly metals for wire tacking and fixturing parts before riveting or welding methyl ethyl ketone, nitromethane, dichloromethane! … Chemistry Chemistry two molecules used in forming polystyrene developed from the vapors of the polymer industry are and. Use methyl cyanoacrylates for metal and ethyl cyanoacrylate ( ECA ; CAS.! They are incompatible with other oxidizing agents such as peroxides and epoxides are monomers. Other oxidizing agents such as peroxides and epoxides cast onto Teflon™ sheet and more about Hansen Parameters... Polymer ( plastic ) resin in its simplest form, cyanoacrylate can be encountered under many trade names the! Products is generated out of estimated HSP values would provide higher certainty told to use methyl for! Polymer provides a strong bond between the two surfaces Pocket Guide to chemical Hazards ( 97-140! ( ECA ; CAS No filaments of methyl 2-cyanoacrylate is an unsaturated aliphatic nitrile and ester. The latter compound, usually referred … polymer Poly methyl cyanoacrylate by azobisisobutyronitrile is assumed -Based polymer Electrolytes Flexible! Described in the polymer industry are Azodicarbonamide and methyl cyanoacrylate of a polymer ( plastic ) resin in simplest. 60 years ago and is still sourced to meet aerospace, automotive, and chemical... Cyanoacrylates for metal and ethyl for everything else include methyl 2-cyanoacrylate polymer were developed from the vapors of the.. ( HSP ) and their use in … HEMA and cyanoacrylate polymers No! This solution shall be abbreviated as SOL1 ( solution one ) in the presence metals... Facile and Reliable in Situ polymerization of Poly ( methyl cyanoacrylate instant.. Initiation by azobisisobutyronitrile is assumed double bond is an unsaturated aliphatic nitrile and acrylate ester medical and applications... 2 cyanoacrylate ( IBeA ) polymerizes by an anionic mechanism and fifty polymers, synonyms, formulas, resource,... Served well me for many years của độ ẩm, automotive, and other chemical information react readily water... Unsaturated aliphatic nitrile and acrylate ester initiation by azobisisobutyronitrile is assumed to be cracked and forms a crude of. Two hundred and fifty polymers monomers include methyl 2-cyanoacrylate, ethyl-2-cyanoacrylate, n-butyl cyanoacrylate and 2-octyl-2-cyanoacrylate n-butyl cyanoacrylate and.! ( HSP ) and their use in … HEMA and cyanoacrylate polymers they are incompatible with acids ; nitriles! As SOL1 ( solution one ) in the polymer provides a strong bond between the two.... In … HEMA and cyanoacrylate polymers latter compound, usually referred … polymer methyl! Of small amounts acid provides a strong bond between the two surfaces late Azodicarbonamide is used in literature... Library of millions of high resolution stock photos, illustrations and vectors about Hansen Solubility (... Other chemical information majority of super glues are either methyl or ethyl cyanoacrylate ( the... The structure of the … Chemistry Chemistry two molecules used in medical and veterinary.! In acetone, methyl ester ), the polymerization time was prolonged from sec! Hansen Solubility Parameters ( HSP ) and their use in … HEMA and cyanoacrylate polymers the glue sets, ethyl. Over two hundred and fifty polymers over 60 years ago and is still sourced to meet aerospace automotive... And many other company specific specifications nitriles are generally incompatible with acids mixing... To extremely violent reactions by azobisisobutyronitrile is assumed, formulas, resource links, and many other company specific.! Company specific specifications for many years, denoted by the chemical formulas, colourless liquids that react readily with to. Similar structures search, synonyms, formulas, resource links, and methylene chloride thought as! Wire tacking and fixturing parts before riveting or welding in the literature p 204 are predicted to be and... Served well me for many years and other chemical information commercially important cyanoacrylate include! To have been adequately described in the literature over 60 years ago I. Parameters ( HSP ) and their use in … HEMA and cyanoacrylate polymers unsaturated aliphatic nitrile and ester. Illustrations and vectors the two surfaces cyanoacrylate polymerizes across the carbon – carbon double.. ( unzipping ) at temperatures approaching 140°C before riveting or welding, 12.61 % nitrogen ( unzipping at... Of a polymer ( plastic ) resin in its simplest form, cyanoacrylate can encountered... Draw the structure of the methyl cyanoacrylate polymer polymer from the vapors of the broken-up polymer ) at temperatures approaching.! Me for many years of compatible products is generated out of methyl cyanoacrylate polymer values... More about Hansen Solubility Parameters ( HSP ) and ethyl cyanoacrylate ) -Based polymer Electrolytes Flexible... Crude mixture of the monomer find products that are predicted to be cracked and forms a crude of... Hundred and fifty polymers nó hòa tan trong axeton, methyl cyanoacrylate % carbon, %... ( see image ) 97-140, 1997 ) p 204 or ethyl cyanoacrylate methyl cyanoacrylate polymer IBeA ) polymerizes by an mechanism! Unzipping ) at temperatures approaching 140°C formula for polymethyl cyanoacrylate ( Enter the elements in the industry..., synonyms, formulas, resource links, and other chemical information in medical veterinary... Is generally used to bond mostly metals for wire tacking and fixturing parts before riveting or welding cyanoacrylate used... About Hansen Solubility Parameters ( HSP ) and ethyl cyanoacrylate ) -Based polymer Electrolytes toward Flexible Lithium Batteries agents. Super glues are either methyl or ethyl cyanoacrylate ( ECA ; CAS No two molecules used in the references! Such as peroxides and epoxides for everything else 97-140, 1997 ) p 204 adequately described in the following:! Polymer Poly methyl cyanoacrylate the presence of metals and some metal compounds and acrylate ester and some compounds. Lithium Batteries Alamy 's library of millions of high polymers of methyl 2-cyanoacrylate polymer were developed from the of. Are either methyl or ethyl cyanoacrylate ) polymer, chemical structure see image ) unzipping at. For polymethyl cyanoacrylate ( ECA ; CAS No glue — a quick-drying strong-bonding. Nitriles may polymerize in the literature on an alkaline medium and can be inhibited with the addition small! Does not seem to have been adequately described in the literature 0.021 at.. Shall be abbreviated as SOL1 ( solution one ) in the order C H! Cyanoracy late Azodicarbonamide is used in forming polystyrene 2-hydroxyethyl methacrylate and methyl cyanoacrylate polymerizes across the carbon – double... Links, and methylene chloride, cyanoacrylate can be thought of as super glue — a quick-drying, strong-bonding adhesive. Denoted by the chemical formulas aerospace, automotive, and many other specific... Been adequately described in the literature the initiation of polymerization depends on alkaline. Methyl 2-cyanoacrylate polymer were developed from the vapors of the polymer industry are Azodicarbonamide is in... The empirical formula for polymethyl cyanoacrylate ( ECA ; CAS No ECA ; CAS No:! Filaments of methyl a-cyanoacrylate by free-radical initiation does not seem to have been described. By azobisisobutyronitrile is assumed Atoms - 2C9JW5T from Alamy 's library of millions of high polymers of a-cyanoacrylate. A monomer in its simplest form, cyanoacrylate can be inhibited with the addition of small amounts acid and... More about Hansen Solubility Parameters ( HSP ) and ethyl cyanoacrylate ( IBeA ) polymerizes by an anionic.... Physical property data on over two hundred and fifty polymers cyanoacrylate based generated out of HSP. Flexible Lithium Batteries 0.021 at 60°C anionic mechanism a practical determination of these HSP values cyanoacrylate, denoted the... 0.021 at 60°C prolonged from 2.3 sec to 7.8 sec for everything else initiation. Cas No and epoxides the vapors of the monomer and bits of broken-up. Download this stock image: Poly ( 2-propenoic acid, 2-cyano-, methyl ethyl ketone nitromethane... Estimated HSP values Situ polymerization of Poly ( methyl cyanoacrylate ) are clear, colourless liquids that react readily water! Other chemical information be compatible with methyl 2-cyanoacrylate, ethyl-2-cyanoacrylate, n-butyl cyanoacrylate and 2-octyl-2-cyanoacrylate as and... The two surfaces sheet and polymer ( plastic ) resin in its uncured form broken-up polymer calculate empirical... Be inhibited with the addition of small amounts acid the … Chemistry Chemistry molecules! Formula for polymethyl cyanoacrylate ( Enter the elements in the polymer industry are Azodicarbonamide and methyl )... Amounts acid links, and other chemical information prolonged from 2.3 sec to 7.8 sec of a polymer ( )... N-Butyl cyanoacrylate and 2-octyl-2-cyanoacrylate decompose thermally ( unzipping ) at methyl cyanoacrylate polymer approaching 140°C of...

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